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Experimental Reduction Of Fe-Oxyhydroxides In Simulated Carbonate and Sulfide/Sulfate Brine: Implications for Paleolake Deposits.

Chidzugwe, Joshua M
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Abstract

Mineral reduction simulations imitating various geochemical environments were conducted over 1 – 30 hours. Ferrihydrite was prepared from solid phases using a solvent-deficient method. In each experiment, ferrihydrite was abiotically reduced with sodium dithionite solution in 1 Molar buffered Na-carbonate and Na-sulfate/sulfide brine at 70°C under nitrogen atmosphere. Six (n=6) and ten (n=10) samples of resultant sulfate/sulfide and carbonate precipitates were collected, respectively. X-Ray Diffractometry (XRD) and Scanning Electron Microscopy (SEM) analytical methods were used to characterize the experimental products. Diagenetic siderite and goethite in carbonate simulations were identified with XRD. Siderite was observed as spherules and platy structures possibly of chukanovite. Calculations using PHREEQ software predicted siderite and pyrite forming in carbonate and sulfate/sulfide brines respectively. The expected pyrite did not precipitate. Rather magnetite, which was unexpected, was formed by either partial reduction of ferrihydrite or partial oxidation of an intermediate reduced phase such as wüstite. Understanding the diagenetic pathways and water-mineral interactions of these systems is necessary for paleoenvironmental reconstruction and for the fidelity of paleomagnetic records.

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Date
2020-05-15
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Research Projects
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Keywords
Ferrihydrite, Diagenesis, Reduction, Siderite, Magnetite.
Citation
Chidzugwe, Joshua M. Experimental Reduction Of Fe-Oxyhydroxides In Simulated Carbonate and Sulfide/Sulfate Brine: Implications for Paleolake Deposits. May 2020, Georgia State University. https://doi.org/10.57709/16155954.
Embargo Lift Date
2020-01-09
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